Nitrile,Latex, Neoprene and Vinyl Gloves: A Primary Source of Contamination for Trace Element and Zn Isotopic Analyses in Geological and Biological Samples          下载免费PDF全文

Marion Garçon  Lucie Sauzéat  Richard W. Carlson  Steven B. Shirey  Mélanie Simon  Vincent Balter  Maud Boyet 《Geostandards and Geoanalytical Research》2017,41(3):367-380

Exogenic contamination is of primary concern for geochemical and biological clean laboratories working with sample sizes at the nanogram or even subpicogram level. Here, we determined sixty trace elements in fifteen different types of gloves from major suppliers world‐wide to evaluate whether gloves could be potential sources of contamination for routine trace element and isotope measurements. We found that all gloves contain some trace elements that can be easily mobilised in significant amounts. In weak acid at room temperature, the tested gloves released up to 17 mg of Zn, more than 1 μg of Mg, Ti, Mn, Fe, Rb, Sr, Zr, Sn, Hf and Pb and between 100 and 1000 ng of Li, Sc, V, Cr, Ni, Cu, Ga, As, Se, Y, Ag, Ba, La, Ce, Nd, Tl and Th. Vinyl gloves released lower quantities of biologically and geologically important elements, with the exception of In and Sn. Isotopic analyses indicate that all gloves share roughly the same Zn isotopic composition (average δ⁶⁶Zn = +0.10 ± 0.32‰ (2s)). A single contact between glove and labware releases an average of ~ 6 ng of Zn and hence can significantly shift δ⁶⁶Zn above the precision level when the amount of Zn determined is below 500 ng.  相似文献   

Impact of the Phaeocystis globosa spring bloom on the intertidal benthic compartment in the eastern English Channel: a synthesis     

Spilmont N  Denis L  Artigas LF  Caloin F  Courcot L  Créach A  Desroy N  Gevaert F  Hacquebart P  Hubas C  Janquin MA  Lemoine Y  Luczak C  Migné A  Rauch M  Davoult D 《Marine pollution bulletin》2009,58(1):55-476

From 1999 to 2005, studies carried out in the frame of regional and national French programs aimed to determine whether the Phaeocystisglobosa bloom affected the intertidal benthic communities of the French coast of the eastern English Channel in terms of composition and/or functioning. Study sites were chosen to cover most of the typical shore types encountered on this coast (a rocky shore, an exposed sandy beach and a small estuary). Both the presence of active Phaeocystis cells and their degradation product (foam) did have a significant impact on the studied shores. The primary production and growth rates of the kelp Saccharina latissima decreased during the bloom because of a shortage of light and nutrient for the macroalgae. On sandy sediments, the benthic metabolism (community respiration and community primary production), as well as the nitrification rate, were enhanced during foam deposits, in relation with the presence of bacteria and active pelagic cells within the decaying colonies. In estuarine sediments, the most impressive impact was the formation of a crust at the sediment surface due to drying foam. This led to anoxic conditions in the surface sediment and resulted in a high mortality among the benthic community. Some organisms also tended to migrate upward and were then directly accessible to the higher trophic level represented by birds. Phaeocystis then created a shortcut in the estuarine trophic network. Most of these modifications lasted shortly and all the systems considered came back to their regular properties and activities a few weeks after the end of the bloom, except for the most impacted estuarine area.  相似文献   

Edifice and substrata deformation induced by intrusive complexes and gravitational loading in the Mull volcano (Scotland)   总被引：1，自引：1，他引：0  

Lucie Mathieu  Benjamin van Wyk de Vries 《Bulletin of Volcanology》2009,71(10):1133-1148

It is likely that the structure of a volcanic edifice can be significantly modified by deformation caused by large, shallow intrusions. Such deformation may interact with that caused by volcano loading. We explore such intrusion-related and loading-related deformation with field evidence and analogue models. To do this we have chosen the eroded Palaeogene Mull volcano (Scotland) that had a major edifice, has well exposed intrusions and significant deformation. There are thin Mesozoic sedimentary rocks forming ductile layers below the volcano, but their thickness is insufficient to allow the gravitational spreading of the volcanic edifice, especially when considering that a thick lava pile covers them. Thus intrusive push may have been the driving force for deformation. The Mull activity migrated toward the northwest, forming three successive intrusive complexes (Centres 1, 2 and 3). Our detailed fieldwork reveals that deformation due to these was accommodated on three levels; along thrust planes in lava sequences, along a décollement located in a thin clay-rich sediment succession and in basement schists. A relative chronology has been established between different groups of structures using dyke and sill cross-cutting relationships. Centre 1 is surrounded by a fold and thrust belt leading to radial expansion. In contrast, Centre 2 and 3 are connected to thrusts located to the south and east, bounded by strike-slip faults, leading to expansion to the southeast. The migration of centres and the directed sliding of the edifice may be related to the presence to the southeast of low-resistance Dalradian basement that failed significantly during growth of Centres 2 and 3. To study the observed relationships we have carried out scaled analogue models. Models are made with fine powder intruded by a viscous magma analogue. The models show an intimate relationship between intrusion growth, uplift of the volcano and subsequent flank sliding. The structures produced can be compared with Mull and suggest that the Centre 1 thrust belt probably formed following edifice gravitational sliding as a consequence of the uplift associated with Centre 1 formation. Centre 2 and 3 are responsible for the sector sliding of the edifice flank toward the southeast as the magmatic complex became more asymmetric. The features observed at Mull and in the models are similar to those seen on active volcanoes, such as Etna, providing a structural framework for their deformation and evolution.  相似文献   

Combined solar and QBO effects on the modes of low-frequency atmospheric variability in the Northern Hemisphere     

Radan Huth  Lucie Pokorn  Josef Bochní ek  Pavel Hejda 《Journal of Atmospheric and Solar》2009,71(13):1471-1483

We examine joint effects of the solar activity and phase of the quasi-biennial oscillation (QBO) on modes of low-frequency variability of tropospheric circulation in the Northern Hemisphere in winter. The winter months (December–March) are stratified by the solar activity into two (below/above median) classes, and each of these classes is subdivided by the QBO phase (west or east). The variability modes are determined by rotated principal component analysis of 500 hPa heights separately in each class of solar activity and QBO phase. Detected are all the modes known to exist in the Northern Hemisphere. The solar activity and QBO jointly affect the shapes, spatial extent, and intensity of the modes; the QBO effects are, however, generally weaker than those of solar activity. For both solar maxima and minima, there is a tendency to the east/west phase of QBO to be accompanied by a lower/higher activity of zonally oriented modes and increased meridionality/zonality of circulation. This means that typical characteristics of circulation under solar minima, including a more meridional appearance of the modes and less activity of zonal modes, are strengthened during QBO-E; on the other hand, circulation characteristics typical of solar maxima, such as enhanced zonality of the modes and more active zonal modes, are more pronounced during QBO-W. Furthermore, the zonal modes in the Euro-Atlantic and Asian sectors (North Atlantic Oscillation, East Atlantic pattern, and North Asian pattern) shift southwards in QBO-E, the shift being stronger in solar maxima.  相似文献   

Fractal dimensions of individual flocs and floc populations in streams     

Dirk H. de Boer  Mike Stone  Lucie M. J. Lvesque 《水文研究》2000,14(4):653-667

The fractal dimension of an individual floc is a measure of the complexity of its external shape. Fractal dimensions can also be used to characterize floc populations, in which case the fractal dimension indicates how the shape of the smaller flocs relates to that of the larger flocs. The objective of this study is to compare the fractal dimensions of floc populations with those of individual flocs, and to evaluate how well both indicate contributions of sediment sources and reflect the nature and extent of flocculation in streams. Suspended solids were collected prior to and during snowmelt at upstream and downstream sites in two southern Ontario streams with contrasting riparian zones. An image analysis system was used to determine area, longest axis and perimeter of flocs. The area–perimeter relationship was used to calculate the fractal dimension, D, that characterizes the floc population. For each sample, the fractal dimension, D_i , of the 28 to 30 largest individual flocs was determined from the perimeter–step‐length relationship. Prior to snowmelt, the mean value of D_i ranged from 1·19 (Cedar Creek, downstream) to 1·22 (Strawberry Creek, upstream and downstream). A comparison of the means using t‐tests indicates that most samples on this day had comparable mean values of D_i . During snowmelt, there was no significant change in the mean value of D_i at the Cedar Creek sites. In contrast, for Strawberry Creek the mean value of D_i at both sites increased significantly, from 1·22 prior to snowmelt to 1·34 during snowmelt. This increase reflects the contribution of sediment‐laden overland flow to the sediment load. At three of the sampling sites, the increase in fractal dimensions was accompanied by a decreases in effective particle size, which can be explained by an increase in bed shear stress. A comparison of fractal dimensions of individual flocs in a sample with the fractal dimensions of the floc populations indicates that both fractal dimensions provide similar information about the temporal changes in sediment source contributions, about the contrasting effectiveness of the riparian buffer zones in the two basins, and about the hydraulic conditions in the streams. Nevertheless, determining the individual fractal dimensions of a set of large flocs in a sample is very time consuming. Using fractal dimensions of floc populations is therefore the preferred method to characterize suspended matter. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

Photometric properties of the δ Scuti star BR Cancri     

Ai-Ying Zhou  E. Rodríguez  A. Rolland  V. Costa 《Monthly notices of the Royal Astronomical Society》2001,323(4):923-929

We present the results of a three-year Johnson V and Strömgren uvby H β photometric study of the δ Scuti star BR Cancri (BR Cnc). Our data sets consist of 1293 discrete differential magnitudes in Johnson V and yellow y filters, 883 in Strömgren v and 239 in ub filters. The Fourier analysis of the data suggests four pulsation frequencies for the variable: f ₁=24.978, f ₂=11.358, f ₃=11.808 and f ₄=27.914 cycle d⁻¹. During the three observing years, the main frequency f ₁ kept its V ( y ) amplitude constant at about 6 mmag but its v amplitude seems to be changing. Amplitude variations for all the three other frequencies are also claimed. The pulsation modes of the frequencies are discussed based on the colour data. Using uvbyβ data and calibrations in the literature, we derive the physical parameters for BR Cnc.  相似文献   

The East Anatolia-Lesser Caucasus ophiolite:An exceptional case of large-scale obduction,synthesis of data and numerical modelling     

Y.Rolland  M.Hässig  D.Bosch  O.Bruguier  R.Melis  G.Galoyan  G.Topuz  L.Sahakyan  A.Avagyan  M.Sosson 《地学前缘(英文版)》2020,11(1):83-108

We present new,geological,metamorphic,geochemical and geochronological data on the East Anatolian-Lesser Caucasus ophiolites.These data are used in combination with a synthesis of previous data and numerical modelling to unravel the tectonic emplacement of ophiolites in this region.All these data allow the reconstruction of a large obducted ophiolite nappe,thrusted for>100 km and up to 250 km on the Anatolian-Armenian block.The ophiolite petrology shows three distinct magmatic series,highlighted by new isotopic and trace element data:(1)The main Early Jurassic Tholeiites(ophiolite s.s.)bear LILEenriched,subduction-modified,MORB chemical composition.Geology and petrology of the Tholeiite series substantiates a slow-spreading oceanic environment in a time spanning from the Late Triassic to the Middle-Late Jurassic.Serpentinites,gabbros and plagiogranites were exhumed by normal faults,and covered by radiolarites,while minor volumes of pillow-lava flows infilled the rift grabens.Tendency towards a subduction-modified geochemical signature suggests emplacement in a marginal basin above a subduction zone.(2)Late Early Cretaceous alkaline lavas conformably emplaced on top of the ophiolite.They have an OIB affinity.These lavas are featured by large pillow lavas interbedded a carbonate matrix.They show evidence for a large-scale OIB plume activity,which occurred prior to ophiolite obduction.(3)Early-Late Cretaceous calc-alkaline lavas and dykes.These magmatic rocks are found on top of the obducted nappe,above the post-obduction erosion level.This series shows similar Sr-Nd isotopic features as the Alkaline series,though having a clear supra-subduction affinity.They are thus interpreted to be the remelting product of a mantle previously contaminated by the OIB plume.Correlation of data from the Lesser Caucasus to western Anatolia shows a progression from back-arc to arc and fore-arc,which highlight a dissymmetry in the obducted oceanic lithosphere from East to West.The metamorphic P-T-t paths of the obduction sole lithologies define a southward propagation of the ophiolite:(1)P-T-t data from the northern Sevan-Akera suture zone(Armenia)highlight the presence and exhumation of eclogites(1.85±0.02 GPa and 590±5℃)and blueschists below the ophiolite,which are dated at ca.94 Ma by Ar-Ar on phengite.(2)Neighbouring Amasia(Armenia)garnet amphibolites indicate metamorphic peak conditions of 0.65±0.05 GPa and 600±20 C with a U-Pb on rutile age of 90.2±5.2 Ma and Ar-Ar on amphibole and phengite ages of 90.8±3.0 Ma and 90.8±1.2 Ma,respectively.These data are consistent with palaeontological dating of sediment deposits directly under(Cenomanian,i.e.>93.9 Ma)or sealing(Coniacian-Santonian,i.e.,≤89.8 Ma),the obduction.(3)At Hinis(NE Turkey)PT-t conditions on amphibolites(0.66±0.06 GPa and 660±20℃,with a U-Pb titanite age of80.0±3.2 Ma)agree with previous P-T-t data on granulites,and highlight a rapid exhumation below a top-to-the-North detachment sealed by the Early Maastrichtian unconformity(ca.70.6 Ma).Amphibolites are cross-cut by monzonites dated by U-Pb on titanite at 78.3±3.7 Ma.We propose that the HT-MP metamorphism was coeval with the monzonites,about 10 Ma after the obduction,and was triggered by the onset of subduction South of the Anatolides and by reactivation or acceleration of the subduction below the Pontides-Eurasian margin.Numerical modelling accounts for the obduction of an"old"~80 Myr oceanic lithosphere due to a significant heating of oceanic lithosphere through mantle upwelling,which increased the oceanic lithosphere buoyancy.The long-distance transport of a currently thin section of ophiolites(<1 km)onto the Anatolian continental margin is ascribed to a combination of northward mantle extensional thinning of the obducted oceanic lithosphere by the Hinis detachment at ca.80 Ma,and southward gravitational propagation of the ophiolite nappe onto its foreland basin.  相似文献   

Late evolution of the southern European Variscan belt: Exhumation of the lower crust in a context of oblique convergence     

Michel Corsini  Yann Rolland 《Comptes Rendus Geoscience》2009,341(2-3):214-223

The south-eastern part of the European Variscan belt forms a zone composed of several crystalline segments: the External Crystalline Massifs of the western Alps, the Maures-Tanneron massif, also Corsica and Sardinia, which are mutually displaced due to the Alpine deformation of the European Paleozoic lithosphere. All these crystalline fragments record similar structural, metamorphic, geochronological and magmatic histories during Paleozoic times. In particular, the Late Carboniferous period (～320–300 Ma) is characterized by crustal-scale folding associated with strike-slip faulting and intracontinental basin formation. In this transpressive context, dome structures exhume partially-molten crust in convergent setting, which is in contradiction with generally accepted models of late orogenic collapse of the Variscan belt. It is suggested that this particular transpressive–obliquely convergent template, exemplified by tectonometamorphic evolution of the Maures-Tanneron massif, is valid for the whole eastern European Variscan margin.  相似文献   

Obduction triggered by regional heating during plate reorganization          下载免费PDF全文

Marc Hässig  Yann Rolland  Thibault Duretz  Marc Sosson 《地学学报》2016,28(1):76-82

The reason for obduction, or tectonic transport of oceanic lithosphere onto continents, is investigated by two‐dimensional thermo‐mechanical numerical modelling based on the geology of the Anatolia–Lesser Caucasus ophiolites. Heating of the oceanic domain and extension induced by far‐field plate kinematics appear to be essential for the obduction of ~80‐Ma‐old oceanic crust over distances exceeding 200 km. Heating of the oceanic lithosphere by mantle upwelling is evidenced by a thick alkaline volcanic series emplaced on top of the oceanic crust 10–20 Ma before obduction, at the onset of Africa–Eurasia convergence. Regional heating reduced the negative buoyancy and strength of the magmatically old lithosphere. Extension facilitated the propagation of obduction by reducing the mantle lithosphere thickness, which led to the exhumation of eclogite‐free continental crust previously underthrusted beneath the ophiolites. This extensional event is ascribed to far‐field plate kinematics resulting from renewed Neotethys oceanic subduction beneath Eurasia.  相似文献   

Direct dating of mid‐crustal shear zones with synkinematic allanite: new in situ U‐Th‐Pb geochronological approaches applied to the Mont Blanc massif     

Bénédicte Cenki‐Tok  James R. Darling  Yann Rolland  Bruno Dhuime  Craig D. Storey 《地学学报》2014,26(1):29-37

Dating the timing of motion on crustal shear zones is of tremendous importance for understanding the assembly of orogenic terranes. This objective is achieved in this paper by combining petrological and structural observations with novel developments in in situ U‐Th‐Pb geochronology of allanite. A greenschist facies shear zone within the Mont Blanc Massif is documented. Allanite is synkinematic and belongs to the mylonitic assemblage. LA‐ICP‐MS U‐Th‐Pb isotope analyses of allanite reveal high contents and highly radiogenic isotopic compositions of the common‐Pb component. The use of measured Pb‐isotope compositions of associated minerals (feldspars and chlorite) is critical for accurate common‐Pb correction, and provides a powerful mechanism for linking allanite growth to the metamorphic assemblage. A mean ²⁰⁸Pb/²³²Th age of 29.44 ± 0.95 Ma is accordingly taken for synkinematic allanite crystallisation under greenschist facies conditions. This age reflects the timing of the Mont Blanc underthrusting below the Penninic Front and highlights the potential of directly dating deformation with allanite.  相似文献